Publications
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Recent Publications
Valentina Pirela, Leire Unanue, Justine Elgoyhen, Javier Ramos, Juan Francisco Vega, Agurtzane Mugica, Manuela Zubitur, Cuong Minh Quoc Le, Abraham Chemtob, Radmila Tomovska, Günter Reiter, Jaime Martín, Alejandro J. Müller. European Polymer Journal (2025) 113721
This work studies how the chemical structure of relatively similar high-sulfur alternating polythioether homopolymers (DMDS-alt-DVE, DMDS-alt-TEGDVE, and DMDS-alt-BDDVE) affects their structural properties, morphology, polymorphism, and crystallization kinetics. Differential scanning calorimetry (DSC) and polarized light optical microscopy (PLOM) experiments revealed a complex crystallization for the samples in which up to three different polymorphic phases were identified: a very low melting crystal form (VL-Tm form), a low melting crystal form (L-Tm form) and a high melting crystal form (H-Tm form), characterized by their corresponding melting temperature ranges and confirmed via Wide-Angle X-ray Scattering (WAXS). A coexistence of negative and positive spherulites was found, and their origin was revealed by atomic force microscopy (AFM), which showed how the lamellar arrangement varied in the samples from predominantly radial to a cross-hatched morphology. (more...)
Gabriele Greco, Benjamin Schmuck, Fredrik G. Bäcklund, Günter Reiter and Anna Rising. ACS Appl. Polym. Mater. 6 (2024) 14342–14350
Recent biotechnological advancements in protein production and development of biomimetic spinning procedures make artificial spider silk a promising alternative to petroleum-based fibers. To enhance the competitiveness of artificial silk in terms of mechanical properties, refining the spinning techniques is imperative. One potential strategy involves the integration of post-spin stretching, known to improve fiber strength and stiffness while potentially offering additional advantages. Here, we demonstrate that post-spin stretching not only enhances the mechanical properties of artificial silk fibers but also restores a higher and more uniform alignment of the protein chains, leading to a higher fiber toughness. (more...)
Raphael Hertel, Maximilian Raisch, Michael Walter, Günter Reiter, Michael Sommer. Angew. Chem. Int. Ed. 2024, e202409369
Sterically distorted donor-acceptor p‑systems, termed DA springs, can be progressively planarized under mechanical load causing a bathochromic shift of the photoluminescence (PL) spectrum. By combining theory and experiment, we here use a simple linear force calibration for two different conformational mechanochromophores to determine molecular forces in polymers from the mechanochromic shift in PL wavelength during multiple uniaxial tensile tests. Two systems are used, i) a highly entangled linear glassy polyphenylene and ii) a covalent elastomeric polydimethylsiloxane network. The mean forces estimated by this method are validated using known threshold forces for the mechanochemical ring-opening reactions of two different spiropyran force probes. The agreement between both approaches underlines that these DA springs provide the unique opportunity for the online monitoring of local molecular forces present in diverse polymer matrices.(more...)
List of Publications
- Time Allowed for Equilibration Quantifies the Preparation Induced Non-equilibrium Behavior of Polymer Films
- Sivasurender Chandran, Rishab Handa, Marwa Kchaou, Samer Al Akhrass, Alexander Semenov, Günter Reiter. ACS Macro Lett. 6 (2017) 1296-1300
- A novel interferometric method for the study of the viscoelastic properties of ultra-thin polymer films determined from nanobubble inflation
- P. Chapuis , P. C. Montgomery, F. Anstotz, A. Leong-Hoï, C. Gauthier, J. Baschnagel, G. Reiter, G. B. McKenna, and A. Rubin. Review of Scientific Instruments 88 (2017) 093901
- Controlling Polymer Crystallization Kinetics by Sample History
- Purushottam Poudel, Sivasurender Chandran, Sumit Majumder and Günter Reiter. Macromol. Chem. Phys. 2017, 1700315
- Morphological Changes of Isotactic Polypropylene Crystals Grown in Thin Films
- Bin Zhang, Jiajia Chen, Baochen Liu, Binghua Wang, Changyu Shen, Renate Reiter, Jingbo Chen, Günter Reiter. Macromolecules 50 (2017) 6210−6217
- Soft electrostatic trapping in nanofluidics
- Michael A. Gerspach, Nassir Mojarad, Deepika Sharma, Thomas Pfohl, and Yasin Ekinci. Microsystems & Nanoengineering (2017) 3, 17051
- Live cell X-ray imaging of autophagic vacuoles formation and chromatin dynamics in fission yeast
- N. Strelnikova, N. Sauter, M. Guizar-Sicairos, M. Göllner, A. Diaz, P. Delivani, M. Chacon, I. M. Tolić, V. Zaburdaev, T. Pfohl, Scientific Reports 7 (2017) 13775
- Second messenger-mediated tactile response by a bacterial rotary motor
- I. Hug, S. Deshpande, K. S. Sprecher, T. Pfohl, U. Jenal, Science 358 (2017) 531-534
- Manipulating the dewetting dynamics of polymer films by creating non-equilibrium conformational states at the interface
- Adrian Linn, Master Thesis 2017
- Induziertes gerichtetes Kristallwachstum einer kristallisierbaren Polymerkomponente innerhalb eines nicht-kristallisierbaren Polymernetzwerks und Untersuchung der resultierenden mechanischen Energie
- Stephan Laule. Inauguraldissertation 2017
- Self-Assembly and Polymerization of Diacetylene Molecules on Epitaxial Graphene
- Fallou Fall, Inaugural-Dissertation zur Erlangung des Doktorgrads der Fakultät für Mathematik und Physik der Universität Freiburg, 2017
- Vesicle Origami and the Influence of Cholesterol on Lipid Packing
- Radu Tanasescu, Martin A. Lanz, Dennis Mueller, Stephanie Tassler, Takashi Ishikawa, Renate Reiter, Gerald Brezesinski, and Andreas Zumbuehl. Langmuir 32 (2016) 4896−4903
- Self-assembly behavior of a rod-like polypeptide at the air-water interface
- Renate Reiter, Frédéric Wintzenrieth, Günter Reiter. Polymer 107 (2016) 379–386
- Covalent Functionalization by Cycloaddition Reactions of Pristine Defect-Free Graphene
- L. Daukiya, C. Mattioli, D. Aubel, S. Hajjar-Garreau, F. Vonau, E.Denys, G. Reiter, J. Fransson, E. Perrin, M-L. Bocquet, C. Bena, A. Gourdon, and L. Simon. ACS Nano 11 (2017) 627–634
- How Molecules with Dipole Moments Enhance the Selectivity of Electrodes in Organic Solar Cells – A Combined Experimental and Theoretical Approach
- Uli Würfel, Martin Seßler, Moritz Unmüssig, Nils Hofmann, Mathias List, Eric Mankel, Thomas Mayer, Günter Reiter, Jean-Luc Bubendorff, Laurent Simon, and Markus Kohlstädt. Adv. Energy Mat. 1600594 (2016)
- Flow-Induced Dendritic β-Form Isotactic Polypropylene Crystals in Thin Films
- Bin Zhang, Binghua Wang, JiaJia Chen, Changyu Shen, Renate Reiter, Jingbo Chen, and Günter Reiter. Macromolecules 49 (2016) 5145−5151
- Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate
- Rainhard Machatschek, Patrick Ortmann, Renate Reiter, Stefan Mecking and Günter Reiter. Beilstein J. Nanotechnol. 7 (2016) 784–798
- When hole extraction determines charge transfer across metal-organic-metal structure
- L. V. Govor, G. Reiter and J. Parisi, EPL, 113 (2016) 57002
- Influence of interfacial trap states on injecting and extracting of charges across a metal-organic interface
- L.V. Govor, G. Reiter and J. Parisi. J. Phys. D: Appl. Phys. 49 (2016) 135306
- Continuous Fused Deposition Modelling of Architectural Envelopes Based on the Shell Formation of Molluscs: A Research Review
- James H. Nebelsick, Christoph Allgaier, Benjamin Felbrich, Daniel Coupek, Renate Reiter, Günter Reiter, Achim Menges, Armin Lechler, Karl-Heinz Wurst. In book: Biomimetic Research for Architecture and Building Construction. Eds. Jan Knippers, Klaus Nickel, Thomas Speck. Springer 2016
- Tunneling of charge carriers across a gold–squaraine interface
- L.V. Govor, G. Reiter and J. Parisi, Physics Letters A 380 (2016) 1493–1498